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Lead-acid technology

How a lead-acid battery is built and why it ages: plates, grids, electrolyte, formation and the failure modes that decide service life.

How to use this cluster

Start from the failure you are trying to prevent, not from the component name. Capacity loss points to sulfation, aging or a charging problem; water loss points to overcharge or a hot environment; grid corrosion points to alloy and service life. Each article below is written to connect a symptom to a design or maintenance cause, so the cluster works as a diagnostic path rather than a glossary.

The three trade-offs that decide a lead-acid design

What this cluster does not cover

Application sizing, group-size selection, wholesale pricing and test standards live in their own clusters. Use the application hub for duty-cycle fit, the data site for dimensions and CCA by group, and the testing site for the standards that govern a performance claim.

TopicWhat it covers
Plate & grid designGrid alloy, plate thickness and the CCA-versus-cycle-life trade-off
Lead oxideThe active material: PbO to PbO₂ and spongy lead
Grid alloyPb-Ca vs Pb-Sb vs Pb-Sn metallurgy
Separator & electrolyteIsolation, acid density and AGM glass mat
Electrolyte specific gravityHydrometer readings as a direct state-of-charge signal
Electrolyte additivesCarbon and other additives and what they change
Formation & chargingThe first charge and the formation profile
Failure modesSulfation, corrosion, water loss and stratification
Lead-acid agingHow the capacity and resistance move over life
VRLAValve-regulated lead-acid: AGM and gel
Gel battery technologySilica-gelled electrolyte and its behaviour
Lead-acid manufacturingFrom oxide to formed battery
Quality controlWhat a factory QC record should contain
Battery materials mapBoth chemistries side by side

A note on service life

Manufacturers quote life in cycles or years, but the number depends on depth of discharge, temperature and charging. Two batteries with the same label can differ by a factor of two in service if one is cycled at 30% depth and the other at 70%. Ask for the cycle-life basis before comparing products.

Related: Lithium-ion technology · Materials & manufacturing · Lead-acid application hub

Frequently asked questions

Which article should I read first?

Start with failure modes if you are diagnosing a returned battery; start with plate and grid design if you are specifying a new product. Both paths link to the electrolyte and formation articles when you need the process detail.

Why does grid alloy matter?

The alloy sets the corrosion rate, water-loss behaviour and deep-cycle tolerance. A calcium alloy is not automatically better than antimony; it is better for low-maintenance float duty, while antimony is more forgiving in repeated deep cycling.

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